Handling concerns, however, severely limit its use. Putting off oil changes and ignoring your check engine light can end up costing you $8,000 or more in major engine repairs later and shorten your vehicle's lifespan by as much as 50,000 miles.. It boils at 12 (so that a trivial pressure will keep it liquid at room temperature) and freezes at a convenient 76. Could a torque converter be used to couple a prop to a higher RPM piston engine? Watch for the fireworks. Boils at 53F. or w/e i introduce myself as. In one particular industrial accident, a spill of 900kg of ClF3 burned through 30cm of concrete and 90cm of gravel beneath. Answer by Paul Mainwood, Degrees in Physics and Philosophy, Doctorate in Philosophy of Physics, on Quora: I dropped organic chemistry as soon as I could. A sample:"If small pieces of yellow phosphorus be added, with stirring, to a solution of chlorine azide in carbon tetrachloride at 0C, the solution gradually becomes turbid, and a succession of slight explosions takes place beneath the liquid. Derek Lowes commentary on drug discovery and the pharma industry. Build the largest LEGO Millennium Falcon to dateIncludes two crews of minifigures - 4 classic crew minifigures: Han Solo, Chewbacca, Princess Leia and C-3PO, plus 3 Star Wars Episode VII/VIII crew minifigures: Older Han Solo, Rey and Finn. A design to accomplish this could have an armor penetrating exterior, then detonate and scatter a bunch of smaller sealed copper spheres like a shotgun blast that would ideally breach the inner walls and then combust. It's the things around them that alter. originally appeared on Quora: the place to gain and share knowledge, empowering people to learn from others and better understand the world. It remains, with its chemical relatives, off in a part of chemical science that's safe from human exploitation. This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). Chlorine monofluoride It is apparently about the most vigorous fluorinating agent known, and is much more difficult to handle than fluorine gas. Pretty self-explanatory. Klorin trifluorida. Barring that, the area must simply be kept cool until the reaction ceases. Chlorine Trifluoride-producing microorganisms. What you're trying to do is to create CIF3 atmosphere to burn enemies, but venting it to space would vent it like any other atmosphere. A few of the other things known to not react with chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene. CIF3 oxidizes so well that it can ignite things that are otherwise fireproof, even famously flame-retardant asbestos. The real question is whether it's all worth using. It can be kept in some of the ordinary structural metals-steel, copper, aluminium, etc. The release of Chlorine Trifluoride to the atmosphere rapidly generates two toxic reaction products: HF and Chlorine Dioxide, [Lombardi, D.A. If, however, this coat is melted or scrubbed off, and has no chance to reform, the operator is confronted with the problem of coping with a metal-fluorine fire. 13(a-1), by visual inspection. As a solid, its white. Required fields are marked *. Numerous explosions, often without assignable cause, have occurred during the experiments. The smallest error in handling it could quite easily kill everyone nearby. Put those in a warhead" and "what would happen if you used this stuff in a mine field, assuming some unobtainium even it couldn't react with?". Even a small piece of space debris could cause problems if it hits the weapon in the right place. What screws can be used with Aluminum windows? This colorless, poisonous, corrosive, and extremely reactive gas condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature). Click the who am i page to see a list a shit ill do for strangers. For dealing with this situation, I have always recommended a good pair of running shoes.". A planet's density tells us more information than its size. So this is true cost Peter is one Coffee Table to one. Boils at 53F. Reactions with many metals give chlorides and fluorides. This question originally appeared on Quora. Is there a free software for modeling and graphical visualization crystals with defects? If it's not perfectly treated, then kaboom goes the vessel. It ishypergolicwith every known fuel, and so rapidly hypergolic that no ignition delay has ever been measured. Or it's just banned by acting rules of engagement. Chlorine trifluoride is prepared by the reactionCl2(g) + 3F2(g) 2ClF3(g). But not here. Contact with organic materials may result in spontaneous ignition. Oxygen, hydrogen peroxide, and the halogens are common examples of these agents. To put it another way; CIF3 is sword-chucks, the deadliest melee weapon (it usually kills the wielder too!). Unsurprisingly, the Nazis were really interested in the military applications of chlorine trifluoride. In general, "it was too crazy even for the Nazis" is an instant disqualifier. Handling concerns, however, severely limit its use. For dealing with this situation, I have always recommended a good pair of running shoes. . Lowe lists with incredulity all the substances he managed to react with it: ammonia (vigorous, this at 100K), water ice (explosion, natch), chlorine (violent explosion, so he added it more slowly the second time), red phosphorus (not good), bromine fluoride, chlorine trifluoride (say what? Image by Koisny under Creative Commons license. How can I make the following table quickly? The molecular geometry of ClF3 is approximately T-shaped, with one short bond (1.598) and two long bonds (1.698). Makes sense, seeing as the only known "safe" way to store CIF3 is to seal it in containers made of steel, iron, nickel, or copper after they've been treated with fluorine gas. The compound also a stronger oxidizing agent than oxygen itself, which also puts it into rare territory. Done on a Dell Dimension laptop computer with a Wacom digital tablet (Bamboo). I mean, maybe? Hes worked for several major pharmaceutical companies since 1989 on drug discovery projects against schizophrenia, Alzheimers, diabetes, osteoporosis and other diseases. The extremely rare blood type is shared by only a handful of people on Earth. About the author Derek Lowe Comments After it has absorbed a bit, it starts destroying your nerves and bones and can ultimately cause cardiac arrest when it gets into your blood stream. As an example of the kind of devastation chlorine trifluoride can have, you only need to consider what happened when almost a ton of this stuff was accidentally spilled inside of a warehouse in the 1950s. Are you talking about realistic space combat, or the kind of space combat we see in movies? It can be kept in some of the ordinary structural metalssteel, copper, aluminum, etc.because of the formation of a thin film of insoluble metal fluoride that protects the bulk of the metal, just as the invisible coat of oxide on aluminum keeps it from burning up in the atmosphere. Meaning its capable of rapidly oxidizing things that would normally be considered practically impossible to set aflame, like asbestos. There's a small leak in a storage unit, and chlorine trifluoride reaches a nearby surface, immediately starting a toxic reaction that will kill many people on the ship because they're trapped in space and have nowhere to hide. However, if this layer is compromised in anyway, or the metal isnt completely dry, chlorine trifluoride will begin to react violently and cause the vessel to explode. CIF3 is its own oxidizer and so doesn't rely on the atmosphere to burn in that sense, but venting the atmosphere will almost certainly remove all of the CIF3, which is gaseous under normal conditions and would be vented along with the atmosphere. If the paper werent laid out in complete grammatical sentences and published in JACS, youd swear it was the work of a violent lunatic. An editorially independent blog, all content is Dereks own, and he does not in any way speak for his employer. Lets look at a couple: First, Dr. Lowe was musing on the ever-present sand-bucket in the corner of chemistry labs, and wondered if there was anything that if dumped in there would just set the sand on fire. Discovery, Inc. or its subsidiaries and affiliates. . Well made ships will have self sealing compartments to deal with hull breaches, so you might do some damage to the area directly adjacent to the impact site. Chloride Trifluoride is available in the condensed form in the market and at pressurized room temperature it turns into a pale-greenish yellow liquid. It's a spacious game preserve, that territory, and over the gate is the ornate motto Noli me tangere. It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that Im sure no one involved ever forgot. First discovered back in the 1930s, chlorine trifluoride is a rather curious chemical that easily reacts, sometimes explosively, with just about every known substance on Earth. The diatomic fluorine dissociates into fierce monatomic fluorine, which binds to the oxygen molecules to produce FOOF. Connect and share knowledge within a single location that is structured and easy to search. "Do not be omitting the stirring, then. To subscribe to this RSS feed, copy and paste this URL into your RSS reader. In particular, CIF3 would make for perfectly destructive flamethrowers and bombs. Untitled - Free download as PDF File (.pdf), Text File (.txt) or read online for free. An explanation of the molecular geometry for the ClF3 (Chlorine trifluoride) including a description of the ClF3 bond angles. It has a density of 3.779 g/L. Then theres Dioxygen Difluoride. If you throw water on the source of the problem, it will get worse. AAAS is a partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, CrossRef and COUNTER. Any equipment that comes into contact with ClF3 must be meticulously cleaned and then passivated, because any contamination left may burn through the unfluorinated material faster than it can re-form. It is known to ignite sand, asbestos, glass, and even ashes of substances that have already burned in oxygen. It is used in rocket fuels and in processing nuclear . 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